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In this review, the possible design strategies for advanced maintenance-free lead-carbon batteries and new rechargeable battery configurations based on lead acid battery technology are critically reviewed. . The lead-acid (PbA) battery was invented by Gaston Planté more than 160 years ago and it was the first ever rechargeable battery. In the charged state, the positive electrode is lead dioxide (PbO2) and the negative electrode is metallic lead (Pb); upon discharge in the sulfuric acid electrolyte. . The lead acid battery has been a dominant device in large-scale energy storage systems since its invention in 1859. It has been the most successful commercialized aqueous electrochemical energy storage system ever since. Recent advancements have focused on enhancing the cycle life and efficiency of these batteries under demanding operating conditions, including high-rate. . Despite an apparently low energy density—30 to 40% of the theoretical limit versus 90% for lithium-ion batteries (LIBs)—lead–acid batteries are made from abundant low-cost materials and nonflammable water-based electrolyte, while manufacturing practices that operate at 99% recycling rates. . Energy storage using batteries is accepted as one of the most important and efficient ways of stabilising electricity networks and there are a variety of different battery chemistries that may be used. All available studies assessing LABs. .
