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However, the development of zinc–iron redox flow batteries (RFBs) remains challenging due to severe inherent difficulties such as zinc dendrites, iron(III) hydrolysis, ion-crossover, hydrogen evolution reactions (HER), and expensive membranes which hinder commercialization. 1,2 This article explores recent advances, challenges, and future directions for zinc-based batteries. Zinc-based batteries are rechargeable, using zinc as the anode material. During. . Aqueous zinc flow batteries are gaining momentum as a safe, cost-effective, and scalable solution for large-scale energy storage, particularly as the global energy sector pivots toward renewables. Among them, iron-based aqueous redox flow batteries (ARFBs) are a compelling choice for future energy storage systems due to their excellent safety, cost-effectiveness and. . As the representative hybrid flow batteries, the zinc-based flow batteries, which utilize the plating-stripping process of the zinc redox couple in anode, have the merits of high energy density, high safety and low cost, and are very promising for stationary energy storage applications.