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One of the more studied manganese oxide-based cathodes is LiMn 2O 4, a cation ordered member of the structural family ( Fd3m). In addition to containing inexpensive materials, the three-dimensional structure of LiMn 2O 4 lends itself to high rate capability by providing a well connected framework for the insertion and de-insertion of Li ions during discharge and charge of the battery. In particular, t.